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Abstract Kepler-51 is a ≲1 Gyr old Sun-like star hosting three transiting planets with radii ≈6–9R_⊕and orbital periods ≈45–130 days. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities (≲0.1 g cm⁻³) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope 10 yr after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses (≲M_Jup) and orbital periods (≲10 yr) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses ≲10M_⊕for the inner transiting planets. Thus, their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the 2:1 mean motion resonance with Kepler-51d implies low orbital eccentricities (≲0.05) and comparable masses (∼5M_⊕) for all four planets, as is seen in other compact multiplanet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer-period planets in a system. 

Abstract The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI Low Resolution Spectrometer observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000× solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities ≤300× solar due to their large corresponding molecular feature amplitudes, preferring values ≥1000× solar and column haze production rates ≥10 −10 g cm −2 s −1 . The steam atmosphere scenario with similarly high haze production rates also exhibits sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights ≥15 g mol −1 are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b’s atmosphere would likely require multiple transits and eclipses using JWST across the near- and mid-infrared, potentially complemented by ground-based high-resolution transmission spectroscopy. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract Close-in giant exoplanets with temperatures greater than 2,000 K (‘ultra-hot Jupiters’) have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble Space Telescope (HST) and Spitzer Space Telescope^1–3. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis^3–12. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS¹³instrument on the JWST. The data span 0.85 to 2.85 μm in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at >6σconfidence) and evidence for optical opacity, possibly attributable to H⁻, TiO and VO (combined significance of 3.8σ). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy-element abundance (‘metallicity’,$${\rm{M/H}}=1.0{3}_{-0.51}^{+1.11}$$ $\mathrm{M/H}=1.03_{-0.51}^{+1.11}$times solar) and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the substellar point that decreases steeply and symmetrically with longitude towards the terminators. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator. 

Abstract Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.